On the thermal stability of some ammonium salts
On the thermal stability of some ammonium salts
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DOI：
10.1016/s0040-6031(01)00585-8
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发表时间：
2001-10-24
影响因子：
3.5
通讯作者：
Olszak-Humienik, M
中科院分区：
文献类型：
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作者：
Olszak-Humienik, M
研究了醋酸铵、硝酸铵和氯化铵的热行为。确定了特定盐的Eyring参数之间的依赖关系。计算了活化自由能随分解温度的变化关系。将转化率的最大值与离子间的化学键能进行了比较。(C)2001 Elsevier Science B.V.保留所有权利。
The thermal behavior of ammonium acetate, nitrate and chloride were investigated. The dependences between Eyring parameters for particular salts were determined. The dependence of Gibbs free energy of activation on decomposition temperature was calculated. The values of maximum of transformation rate were compared with energies of chemical bonds between ions. (C) 2001 Elsevier Science B.V. All rights reserved.