Microstructures related to the ferroelectric properties in BiFeO3-BaTiO3

Microstructures related to the ferroelectric properties in BiFeO3-BaTiO3
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BiFeO3-BaTiO3 中与铁电性能相关的微观结构

DOI:
10.14723/tmrsj.33.27
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发表时间:
2008
期刊:
Transactions-Materials Research Society of Japan
影响因子:
--
通讯作者:
S. Mori
S. Mori
中科院分区:
--
文献类型:
--
作者:
S. Kitagawa;Y. Horibe;K. Yoshii;Muneyasu Suzuki;Y. Noguchi;S. Nishihara;Y. Hosokoshi;S. Mori

文献摘要

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(1-x)BiFeOrxBaTi0 3中与铁电(FE)性能相关的微观结构主要通过透射电子显微镜,结合传统的磁和介电测量进行了研究。发现在x=0.25的化合物中,随着BaTi0 3浓度(x)的增加,BiFe0 3中宏观尺寸的FE畴结构转变为20 ~ 30nm尺寸的精细FE微观结构。此外,由于x=0.33化合物在室温下的应变场,我们发现了典型的花呢样对比度。我们通过获取实空间图像仔细研究了x=0.25化合物中FE微畴的空间分布,并确定了每个FE微畴中自发极化的空间构型。
Microstructures related to the ferroelectric (FE) properties in (1-x)BiFeOrxBaTi0 3 were examined mainly by a transmission electron microscopy, in combination with conventional magnetic and dielectric measurements. It was found that macroscopic-sized FE domain structures in BiFe0 3 changed into fine FE microstructures with the 20-30nm size in the x=0.25 compound, as the BaTi0 3 concentration (x) was increased. In addition, we found characteristic tweed-like contrast due to the strain field in the x=0.33 compound at room temperature. We carefully investigated a spatial distribution of the FE microdomains in the x=0.25 compound by obtaining real-space images and determined the spatial configuration of the spontaneous polarization in each FE microdomains.