REVERSIBLE HYDRIDE TRANSFER FROM 1-METHYL-1,4-DIHYDRONICOTINAMIDE (1,4-MeNDH) TO MeND+ IODIDE YIELDING 1,6-MeNDH
REVERSIBLE HYDRIDE TRANSFER FROM 1-METHYL-1,4-DIHYDRONICOTINAMIDE (1,4-MeNDH) TO MeND+ IODIDE YIELDING 1,6-MeNDH
复制标题
1-甲基-1,4-二氢烟酰胺 (1,4-MeNDH) 的可逆氢化物转移至碘化物生成 1,6-MeNDH
DOI：
10.1246/cl.1977.13
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发表时间：
1977
影响因子：
1.6
通讯作者：
Michio. Kobayashi
中科院分区：
文献类型：
--
作者：
H. Minato;Takao Ito;Michio. Kobayashi
发现1-甲基-1，4-二氢烟酰胺（1，4-MeNDH）与MeND+在D2 O中在34°C下的反应产生1，6-MeNDH，并且发现1，6-MeNDH与MeND+的反应产生1，4-MeNDH。当任一1-甲基二氢烟酰胺与催化量的MeND+混合时，在1，6-MeNDH（18%）和1，4-MeNDH（82%）之间建立平衡。
The reaction of 1-methyl-1,4-dihydronicotinamide (1,4-MeNDH) with MeND+ in D2O at 34°C was found to yield 1,6-MeNDH, and the reaction of 1,6-MeNDH with MeND+ was found to yield 1,4-MeNDH. An equilibrium was established between 1,6-MeNDH(18%) and 1,4-MeNDH(82%) when either of the 1-methyldihydronicotinamides was mixed with a catalytic amount of MeND+.