STUDIES OF AUSTRALIAN SOFT CORALS .7. 2 NEW DITERPENES FROM AN UNKNOWN SPECIES OF SOFT CORAL (GENUS LOBOPHYTUM)
STUDIES OF AUSTRALIAN SOFT CORALS .7. 2 NEW DITERPENES FROM AN UNKNOWN SPECIES OF SOFT CORAL (GENUS LOBOPHYTUM)
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DOI：
10.1071/ch9781303
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发表时间：
1978-01-01
影响因子：
1.1
通讯作者：
STOKIE, GJ
中科院分区：
文献类型：
--
作者：
BOWDEN, BF;COLL, JC;STOKIE, GJ
从一种软珊瑚中分离出两个新的二萜化合物。一种是含有新的α-环己基二萜（1），而第二个化合物是软珊瑚文献中独特的，因为它具有13元碳环。这可能是由于珊瑚中（1）的重排。结构归属严重依赖于光谱学，但与化学转化一致。
Two new diterpenes have been isolated from a soft coral of the genus Lobophytum. One was a cembranolide diterpene (1) containing a novel .alpha.-keto epoxide grouping while the 2nd compound unique to the soft coral literature in that it possessed a 13-membered carbocyclic ring. This was presumably derived from rearrangement of (1) within the coral. The structure assignments relied heavily on spectroscopy, but were consistent with chemical transformation.