X-RAY STUDY OF THE THERMAL-EXPANSION ANISOTROPY IN AGGAS2 AND AGINS2 COMPOUNDS OVER THE TEMPERATURE-RANGE FROM 80 TO 650-K

X-RAY STUDY OF THE THERMAL-EXPANSION ANISOTROPY IN AGGAS2 AND AGINS2 COMPOUNDS OVER THE TEMPERATURE-RANGE FROM 80 TO 650-K
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DOI:
10.1002/pssa.2210910218
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发表时间:
1985-01-01
期刊:
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH
影响因子:
--
通讯作者:
ORLOVA, NS
ORLOVA, NS
中科院分区:
其他
文献类型:
--
作者:
BODNAR, IV;ORLOVA, NS

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在80 ~ 650 K温度范围内,用X射线衍射法测定了AgGaS 2和AgInS 2化合物的晶格常数α和c随温度的变化.这些数据用于计算垂直于主轴(α <$)和平行于主轴(α <$)的热膨胀系数,以及A <$C(αAC)和B <$C(αBC)键的热膨胀系数。结果表明,在几乎整个研究温度范围内,这两种化合物的膨胀系数α B和αBCare均为负值,而α C和α AC均为正值。
The lattice parameters α andcof the AgGaS2and AgInS2compounds are determined as a function of temperature by X‐ray diffraction method in the temperature range from 80 to 650 K. The data are used to evaluate the coefficients of thermal expansion, perpendicular (α⟂) and parallel (α∥) to the principal axis, and the thermal expansion of the AC (αAC) and BC (αBC) bonds. It is found that for the two compounds almost over the whole investigated temperature range the coefficients of expansion α∥ and αBCare negative while the coefficients α⟂ and αACare positive.