A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp3-H centers
A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp3-H centers
复制标题
具有 C-sp3-H 中心的炔酸酯的无金属炔加成/1,4-芳基迁移/脱羧级联反应
DOI：
10.1039/c5ob02478a
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发表时间：
2016-01-01
影响因子：
3.2
通讯作者：
Liu, Li
中科院分区：
文献类型：
--
作者：
Kong, De-Long;Cheng, Liang;Liu, Li
报道了五种不同类型的自由基前驱体(R-H)通过炔加成/1，4-芳基迁移/脱羧基的无金属级联反应，该反应可以方便地获得功能化的乙烯基产品，其“R”和质子位于所形成的双键的相同碳上。
A metal-free cascade reaction of aryl alkynoates with five different types of radical precursors (R-H) through an yne-addition/1,4-aryl migration/decarboxylation process was reported, which allowed facile and convenient access to functionalized vinyl products with "R" and protons located at the identical carbon of the formed double bond.