Stable Single-Crystalline Body Centered Cubic Fe Nanoparticles

Stable Single-Crystalline Body Centered Cubic Fe Nanoparticles
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DOI:
10.1021/nl200110t
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发表时间:
2011-04-01
期刊:
影响因子:
10.8
通讯作者:
Sun, Shouheng
Sun, Shouheng
中科院分区:
材料科学1区
文献类型:
--
作者:
Lacroix, Lise-Marie;Huls, Natalie Frey;Sun, Shouheng

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We report,a facile synthesis of body centered cubic (bcc) Fe nanoparticles (NPs) via the thermal decomposition of iron pentacarbonyl, Fe(CO)(5), in the presence of hexadecylammonium chloride. These bcc-Fe NPs exhibit a drastically increased stability and magnetic moment (M-s = 164 A . m(2) . kg(-1) (Fe)) even in physiological solutions, and have much enhanced magnetic imaging contrast (r(2) = 220 s(-1) . mM(-1)) and heating (SAR = 140 W . g(Fe)(-1)) effects. They may serve as robust probes for imaging and therapeutic applications.