Ratio of Ionic Conductivity to Tracer Diffusion in Interstitialcy Migration
Ratio of Ionic Conductivity to Tracer Diffusion in Interstitialcy Migration
复制标题
间隙迁移中离子电导率与示踪剂扩散的比率
DOI：
10.1103/physrev.101.1210
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发表时间：
1956
期刊：
影响因子：
--
通讯作者：
A. B. Lidiard
中科院分区：
文献类型：
--
作者：
C. Mccombie;A. B. Lidiard
Compton'的HE实验结果表明，对于AgCl晶体中由于间隙银离子的存在而引起的部分离子迁移，离子电导率与示踪剂扩散的比值大大超过了爱因斯坦值。这里将显示，根据科赫和瓦格纳所讨论的、塞茨所描述的相互作用机制，这个比值的值大约是爱因斯坦值的三倍。
HE experimental results of Compton' suggest that, for that part of the ionic migration in AgCl crystals which is due to the presence of interstitial silver ions, the ratio of ionic conductivity to tracer diffusion considerably exceeds theEinstein value. It will be shown here that a value of this ratio about three times the Einstein value is to be expected for migration by the ieterstitialcy mechanism discussed by Koch and Wagner'and so described by Seitz.