Mobility of Cr and V in Spent Oil Shale: Impact of Thermal Treatment

Mobility of Cr and V in Spent Oil Shale: Impact of Thermal Treatment
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废油页岩中 Cr 和 V 的迁移率:热处理的影响

DOI:
10.1016/j.proeps.2013.03.001
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发表时间:
2013
期刊:
Procedia Earth and Planetary Science
影响因子:
--
通讯作者:
Illner P.
Illner P.
中科院分区:
--
文献类型:
--
作者:
Gütlein A;Kersten M;Feinstein S;Illner P.

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研究人员评估了废油页岩样品在用于发电的好氧燃烧或用于页岩油开采的厌氧重整过程中可能释放的铬和钒。由于铬酸盐的形成,燃烧后的样品释放出的铬比还原或原始样品多。钒的行为正好相反,从馏出比从好氧燃烧的样品释放更多的V,可能是由于减少了钒基阳离子的形成。
Spent oil shale samples were evaluated for potential chromium and vanadium release upon aerobic combustion used in power generation, or anaerobic retorting used in shale oil recovery. Combusted samples released more Cr than retorted or raw samples due to chromate formation. The behavior of vanadium was just opposite in that more V was released from retorted than from aerobically combusted samples, probably due to reduced vanadyl cation formation.
油页岩燃烧过程中微量元素的途径——浸出过程中微量元素可用性的线索
DOI: --
发表时间: 1988
期刊:
影响因子: --
作者:
M. Shirav;Y. Zimmels
通讯作者: Y. Zimmels