Coordination nanosheets (CONASHs): strategies, structures and functions
Coordination nanosheets (CONASHs): strategies, structures and functions
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DOI：
10.1039/c7cc00810d
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发表时间：
2017-05-28
影响因子：
4.9
通讯作者：
Nishihara, Hiroshi
中科院分区：
文献类型：
--
作者：
Sakamoto, Ryota;Takada, Kenji;Nishihara, Hiroshi
纳米片，这是二维聚合物材料，仍然是最活跃的研究领域之一，化学和物理这十年。通常，纳米片是由块状晶体层状材料形成的无机材料，具有迷人的性质和功能。一种新兴的替代方案是含有有机分子成分的分子基纳米片。基于分子的纳米片提供了很大的多样性，因为它们的分子、离子和原子成分可以被选择和组合以产生各种各样的纳米片。本文重点介绍了配位纳米片（CONASH），一类基于分子的纳米片，包括有机配体分子和金属离子/原子在一个框架内与配位键连接。在引言之后，第2节描述了CONASH，包括它们的定义、设计、合成程序和表征技术。第3节介绍了CONASH的各种示例，第4节探讨了它们的功能和可能的应用。第五部分对CONASH的研究领域进行了展望。
Nanosheets, which are two-dimensional polymeric materials, remain among the most actively researched areas of chemistry and physics this decade. Generally, nanosheets are inorganic materials created from bulk crystalline layered materials and have fascinating properties and functionalities. An emerging alternative is molecule-based nanosheets containing organic molecular components. Molecule-based nanosheets offer great diversity because their molecular, ionic, and atomic constituents can be selected and combined to produce a wide variety of nanosheets. The present article focuses on coordination nanosheets (CONASHs), a class of molecule-based nanosheets comprising organic ligand molecules and metal ions/atoms in a framework linked with coordination bonds. Following the Introduction, Section 2 describes CONASHs, including their definition, design, synthetic procedures, and characterisation techniques. Section 3 introduces various examples of CONASHs, and Section 4 explores their functionality and possible applications. Section 5 describes an outlook for the research field of CONASHs.