Palladium(0) Nanoparticle Catalyzed Cross-Coupling of Allyl Acetates and Aryl and Vinyl Siloxanes
Palladium(0) Nanoparticle Catalyzed Cross-Coupling of Allyl Acetates and Aryl and Vinyl Siloxanes
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DOI：
10.1021/jo802214m
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发表时间：
2008-12-05
影响因子：
3.6
通讯作者：
Ranu, Brinclaban C.
中科院分区：
文献类型：
--
作者：
Dey, Raju;Chattopadhyay, Kalicharan;Ranu, Brinclaban C.
The cross-coupling of allyl acetates and aryl and vinyl siloxanes proceeds readily by the catalysis of in situ generated palladium(0) nanoparticles. The reactions are stereoselective, and (E)-coupling products are obtained both from cis and trans allyl acetates. The coupling with vinyl siloxanes provides a novel protocol for the synthesis of 1,4-pentadienes.
