Long-term durable silicon photocathode protected by a thin Al2O3/SiOx layer for photoelectrochemical hydrogen evolution

Long-term durable silicon photocathode protected by a thin Al2O3/SiOx layer for photoelectrochemical hydrogen evolution
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DOI:
10.1039/c3ta14443g
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发表时间:
2014-01-01
影响因子:
11.9
通讯作者:
Bang, Jin Ho
Bang, Jin Ho
中科院分区:
材料科学2区
文献类型:
--
作者:
Choi, Mi Jin;Jung, Jin-Young;Bang, Jin Ho

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长期稳定地产生H-2对p-Si光电阴极至关重要。然而,随着时间的推移,Si光电极的氧化显著劣化其性能。这项研究表明,薄的Al 2 O3层沉积在Si上,可以防止氧化,也降低过电位,通过表面钝化效应。
The long-term steady production of H-2 is vital for p-Si photocathodes. However, the oxidation of a Si photoelectrode substantially deteriorates its performance, over time. This study demonstrates that a thin Al2O3 layer deposited over the Si can prevent oxidation and also reduce overpotential, via a surface passivation effect.