A Procedure for Transforming indoles into Indolequinones
A Procedure for Transforming indoles into Indolequinones
复制标题
DOI：
10.1021/jo502509s
复制
发表时间：
2015-01-16
影响因子：
3.6
通讯作者：
Sperry, Jonathan
中科院分区：
文献类型：
--
作者：
Eastabrook, Andrew S.;Wang, Christy;Sperry, Jonathan
描述了一种将一系列结构多样的、容易获得的吲哚衍生物转化为它们相应的吲哚醌的方法。三步路线从铱催化的C-H硼基化反应开始，得到7-硼基吲哚，经氧化水解得到7-羟基吲哚。随后的氧化提供吲哚醌。
A procedure that converts a series of structurally diverse, readily available indole derivatives to their corresponding indolequinones is described. The three-step route commences with an iridium catalyzed C-H borylation to give a 7-borylindole that upon oxidationhydrolysis affords the 7-hydroxyindole. Subsequent oxidation provides the indolequinone.