Ionization potentials of small carbon clusters

Ionization potentials of small carbon clusters
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小碳团簇的电离势

DOI:
10.1063/1.464591
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发表时间:
1993
期刊:
影响因子:
--
通讯作者:
J. Eyler
J. Eyler
中科院分区:
--
文献类型:
--
作者:
R. Ramanathan;J. A. Zimmerman;J. Eyler

文献摘要

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小碳团簇(Cn,n=3-6)的电离势(IP's)在傅里叶变换离子回旋共振质谱仪中通过电荷转移方法被限定为十分之几eV的不确定度。所获得的值进行比较,以前确定的实验和理论值。在碳簇离子和电荷转移参比化合物之间观察到了除电荷转移以外的几种有趣的反应。这些反应的产物进行了报道和讨论。
Ionization potentials (IP’s) of small carbon clusters (Cn, n=3–6) have been bracketed with an uncertainty of a few tenths of an eV by charge‐transfer methods in a Fourier transform ion cyclotron resonance mass spectrometer. Values obtained are compared to previously determined experimental and theoretical values. Several interesting reactions other than charge‐transfer were observed between the carbon cluster ions and the charge‐transfer reference compounds. The products of these reactions are reported and discussed.