Silver halide complexes of a borane/bis(phosphine) ligand

Silver halide complexes of a borane/bis(phosphine) ligand
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DOI:
10.1039/c9dt02100k
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发表时间:
2019-07-21
影响因子:
4
通讯作者:
Ozerov, Oleg V.
Ozerov, Oleg V.
中科院分区:
化学2区
文献类型:
--
作者:
Cao, Yihan;Shih, Wei-Chun;Ozerov, Oleg V.

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制备了硼烷/双(膦)配体的卤化银配合物并进行了表征。与AgF,硼烷提取氟化物,产生两性离子络合物。对于AgCl, AgBr和AgI,卤化物与Ag保持协调,很少或没有Ag- b相互作用。
Silver halide complexes of a borane/bis(phosphine) ligand have been prepared and characterized. With AgF, the borane abstracts fluoride, resulting in a zwitterionic complex. With AgCl, AgBr, and AgI, the halide stays coordinated to Ag, with little to no Ag-B interaction.