Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes
Energy Resonance Crossing Controls the Photoluminescence of Europium Antenna Probes
复制标题
能量共振交叉控制铕天线探针的光致发光
DOI：
10.1002/anie.201701575
复制
发表时间：
2017
影响因子：
16.6
通讯作者：
Dolg Michael
中科院分区：
文献类型：
--
作者：
Zhang Qiangqiang;Wu Liangliang;Cao Xiaoyan;Chen Xuebo;Fang Weihai;Dolg Michael
The energy transfer pathways in lanthanide antenna probes cannot be comprehensively rationalized by the currently available models, and their elucidation remains to be a challenging task. On the basis of quantum‐chemical ab initio calculations of representative europium antenna complexes, an innovative energy resonance model is proposed, which is controlled by an overall nonet–quintet intersystem crossing on the basis of spin–orbit coupling among the sublevels of the involved states.
