Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides
Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides
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DOI：
10.1007/s11244-012-9824-0
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发表时间：
2012-07-01
影响因子：
3.6
通讯作者：
Beller, Matthias
中科院分区：
文献类型：
--
作者：
Schareina, Thomas;Wu, Xiao-Feng;Beller, Matthias
第一个铜催化的芳基卤化物的三氟甲基化反应是利用廉价的三氟乙酸酯开发的。提供低浓度的最具经济吸引力和原子效率的三氟甲基化试剂，这种新的协议是有利的相比，已知的程序在经济上和生态上。
The first copper-catalyzed trifluoromethylation of aryl halides was developed that utilizes inexpensive trifluoroacetates. Providing low concentrations of the most economically attractive and atom-efficient trifluoromethylation reagent this new protocol is advantageous compared to known procedures both economically and ecologically.