Do inner shells of double-walled carbon nanotubes fluoresce?

Do inner shells of double-walled carbon nanotubes fluoresce?
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双壁碳纳米管的内壳会发出荧光吗?

DOI:
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发表时间:
2009
期刊:
Nano letters (Print)
影响因子:
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通讯作者:
R. Weisman
R. Weisman
中科院分区:
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文献类型:
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作者:
D. Tsyboulski;Y. Hou;N. Fakhri;Saunab Ghosh;Ru Zhang;S. Bachilo;M. Pasquali;Liwei Chen;Jie Liu;R. Weisman

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报道的双壁碳纳米管(DWCNTs)的内壳层的荧光是一个有趣的和潜在的有用的性质。采用体相和单分子相结合的方法研究了DWCNT样品中近红外发射体的光谱、化学猝灭、机械刚度、丰度、密度和TEM图像。发现DWCNT内壳荧光比SWCNT荧光弱至少10,000倍。DWCNT样品的可观察到的近红外发射归因于SWCNT杂质。
The reported fluorescence from inner shells of double-walled carbon nanotubes (DWCNTs) is an intriguing and potentially useful property. A combination of bulk and single-molecule methods was used to study the spectroscopy, chemical quenching, mechanical rigidity, abundance, density, and TEM images of the near-IR emitters in DWCNT samples. DWCNT inner shell fluorescence is found to be weaker than SWCNT fluorescence by a factor of at least 10,000. Observable near-IR emission from DWCNT samples is attributed to SWCNT impurities.