Recent advances in nitrogen fixation upon vanadium complexes
Recent advances in nitrogen fixation upon vanadium complexes
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DOI：
10.1016/j.ccr.2018.11.005
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发表时间：
2019-02
影响因子：
20.6
通讯作者：
Yoshiaki Tanabe;Y. Nishibayashi
中科院分区：
文献类型：
--
作者：
Yoshiaki Tanabe;Y. Nishibayashi
虽然钒是固氮的关键元素之一，但直到最近才开发出使用钒络合物催化还原N2为NH3、N2 H4或甲硅烷基胺的方法。本文综述了钒化合物转化N2的历史背景、钒-二氮配合物的制备和反应活性，以及钒配合物催化N2转化为NH3/N2 H4/（Me 3Si）3 N的最新研究进展。
Although vanadium is one of the key elements in nitrogen fixation, catalytic reduction of N2into NH3, N2H4, or silylamines using vanadium complexes has not been developed until very recently. This review article describes the historical background on the transformation of N2using vanadium compounds, preparation and reactivity of vanadium–dinitrogen complexes, and very recent advances on the catalytic conversion of N2into NH3/N2H4/(Me3Si)3N using vanadium complexes as catalysts.