Thermally Stable Cyclopolymer From the Ether Dimer of Adamantyl Alpha-Hydroxymethylacrylate
Thermally Stable Cyclopolymer From the Ether Dimer of Adamantyl Alpha-Hydroxymethylacrylate
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来自α-羟甲基丙烯酸金刚烷基醚二聚体的热稳定环聚合物
DOI：
10.1021/ma00069a054
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发表时间：
1993
期刊：
影响因子：
5.5
通讯作者：
L. Mathias
中科院分区：
文献类型：
--
作者：
Takashi Tsuda;L. Mathias
α-羟甲基丙烯酸金刚烷酯醚二聚体通过自由基或自发环化聚合得到可溶性聚合物[CH 2 C（CO2 Ad）[CH 2 OCH 2 ]C（CO2 Ad）] n（Ad=金刚烷基，Mn = 40000，Mw = 290000）。聚合物表现出375°C的5%重量损失温度。
The soluble polymer [CH 2 C(CO 2 Ad)[CH 2 OCH 2 ]C(CO 2 Ad)] n (Ad= adamantyl) with M n = 40000 and M w = 290000) was obtained by free radical or spontaneous cyclopolymerization of the ether dimer of adamantyl α-hydroxymethylacrylate. The polymer exhibited a 5% weight loss temperature of 375°C