Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide
Photocatalytic reductive dechlorination of chlorobenzene to benzene in 2-propanol suspension of metal-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide
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DOI：
10.1039/c0cc00589d
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Kominami, Hiroshi
中科院分区：
文献类型：
--
作者：
Fuku, Kojirou;Hashimoto, Keiji;Kominami, Hiroshi
氯苯在异丙醇悬浮液中的钯和铑负载的钛（IV）氧化物纳米晶体在溶解的氢氧化钠的存在下在脱气条件下的光催化反应，其中2-丙醇，金属负载（钯和铑）和氢氧化钠有效地充当空穴清除剂，助催化剂和氯化物固化剂，分别定量地得到苯和氯离子与高化学计量比。
Photocatalytic reaction of chlorobenzene in 2-propanol suspension of palladium- and rhodium-loaded titanium(IV) oxide nanocrystals in the presence of dissolved sodium hydroxide under deaerated conditions, in which 2-propanol, metal loaded (palladium and rhodium) and sodium hydroxide effectively acted as hole scavenger, co-catalyst and chloride solidifier, respectively, quantitatively gave benzene and chloride ions with a high stoichiometry.