An X-ray diffuse scattering study of domains in F(CF2)10(CH2)2OH monolayers at the hexane-water interface

An X-ray diffuse scattering study of domains in F(CF2)10(CH2)2OH monolayers at the hexane-water interface
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DOI:
10.1209/epl/i2002-00608-x
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发表时间:
2002-04-01
期刊:
EUROPHYSICS LETTERS
影响因子:
--
通讯作者:
Schlossman, ML
Schlossman, ML
中科院分区:
其他
文献类型:
--
作者:
Li, M;Tikhonov, AM;Schlossman, ML

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X射线离镜漫散射被用来直接探测F(CF 2)(10)(CH 2)(2)OH在己烷-水界面上吸附的单分子膜中畴的统计分布。这些领域出现非常接近从单层固体到气相的过渡。该域具有近似1.5 μ m的几乎恒定的半径和随温度从2到8 μ m变化的最近邻分离。磁畴具有平衡尺寸的证据表明,可以确定磁畴线张力,λ(t)约为3 × 10(-11)N。
X-ray off-specular diffuse scattering is used to directly probe the statistical distribution of domains in monolayers of F(CF2)(10)(CH2)(2)OH adsorbed at the hexane-water interface. These domains appear very near a transition from a monolayer solid to gas phase. The domains have a nearly constant radius of approximate to 1.5 mum and a nearest-neighbor separation that varies from 2 to 8 mum with temperature. Evidence that the domains are of equilibrium size suggests that the domain line tension, lambda(t) approximate to 3 x 10(-11) N, can be determined.