Asymmetric organocatalytic diboration of alkenes
Asymmetric organocatalytic diboration of alkenes
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DOI：
10.1039/c2ob26079d
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发表时间：
2012-01-01
影响因子：
3.2
通讯作者：
Fernandez, Elena
中科院分区：
文献类型：
--
作者：
Bonet, Amadeu;Sole, Cristina;Fernandez, Elena
使用手性醇原位形成刘易斯酸-碱 *RO- ->双（频哪醇合）二硼加合物，提供了在烯烃的有机催化二硼化中诱导不对称的机会，并补充了充分建立的过渡金属介导的对映选择性二硼化。
The use of chiral alcohols to form the Lewis acid-base *RO- -> bis(pinacolato)diboron adduct, in situ, provides an opportunity to induce asymmetry in the organocatalytic diboration of alkenes and complements the well established transition metal-mediated enantioselective diboration.