Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation
Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation
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DOI：
10.1039/b613655a
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Mulvey, Robert E.
中科院分区：
文献类型：
--
作者：
Armstrong, David R.;Clegg, William;Mulvey, Robert E.
苯可以很容易地1，4-dideprotonated化学计量反应与两个当量的协同混合物（Bu 2 Zn）-Bu-t，NaTMP和TMEDA，得到一个独特的1，4-dizincated苯产品，其特征在于通过X-射线晶体学和NMR光谱以及理论建模的DFT计算研究;相关的协同dimagnetisation苯也报道。
Benzene can be easily 1,4-dideprotonated stoichiometrically on reaction with two equivalents of a synergic mixture of (Bu2Zn)-Bu-t, NaTMP and TMEDA to give a unique 1,4-dizincated benzene product which has been characterised by X-ray crystallography and NMR spectroscopy as well as modelled theoretically by DFT computational studies; a related synergic dimagnesiation of benzene is also reported.