Synthesis of 1,2-and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C-H Bonds
Synthesis of 1,2-and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C-H Bonds
复制标题
DOI：
10.1021/ja8063827
复制
发表时间：
2008-10-29
影响因子：
15
通讯作者：
Yu, Jin-Quan
中科院分区：
文献类型：
--
作者：
Giri, Ramesh;Yu, Jin-Quan
一个钯（II）催化的反应协议，用于直接羧化的苯甲酸和苯乙酸衍生物，形成二羧酸已经开发。该反应条件也适用于乙烯基C-H键的羧化反应。首次合成了羧酸类C-H插入钯-芳基配合物。
A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C-H bonds, The first C-H insertion Pd-aryl complex from carboxylic acids has been characterized by X-ray crystallography.