Hydrogenative Cross-coupling of Internal Alkynes and Aryl Iodides by Palladium/Copper Cooperative Catalysis
Hydrogenative Cross-coupling of Internal Alkynes and Aryl Iodides by Palladium/Copper Cooperative Catalysis
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DOI：
10.1246/cl.170961
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发表时间：
2017-12
影响因子：
1.6
通讯作者：
Kazuhiko Semba;Ryohei Kameyama;Y. Nakao
中科院分区：
文献类型：
--
作者：
Kazuhiko Semba;Ryohei Kameyama;Y. Nakao
在钯/铜协同催化下，内炔和芳基碘的氢化交叉偶联反应以中等至良好的产率和立体选择性得到了一系列三芳基乙烯。在所应用的催化条件下，容许各种官能团，包括甲硅烷基醚、氯、氟、三氟甲基和胺取代基。
The hydrogenative cross-coupling of internal alkynes and aryl iodides by palladium/copper cooperative catalysis furnished a range of triarylethenes in moderate to good yield and stereoselectivity. Under the applied catalytic conditions, various functional groups, including silylether, chloro, fluoro, trifluoromethyl, and amine substituents, are tolerated.