Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions
Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions
复制标题
DOI：
10.1039/b010227j
复制
发表时间：
2001
期刊：
影响因子：
--
通讯作者：
Yan Xu;Dunru Zhu;Zijian Guo;Yu Shi;Kou-Lin Zhang;X. You
中科院分区：
文献类型：
--
作者：
Yan Xu;Dunru Zhu;Zijian Guo;Yu Shi;Kou-Lin Zhang;X. You
合成了两种新型十六金属氧簇化合物{Ni[(NH2)2(C2H4)2NH]2}3[PMoVI5MoV3VIV8O44]·[(NH2)2(C2H4)2NH]·H2O 1 和{Co[(NH2)2(C2H4)2NH]2}2Na[PMoVI6MoV2VIV8O44]·8H2O 2水热法，并通过X射线晶体学表征，表明1的阴离子具有新颖的四封端模式，并且在2中观察到第一个十六金属-氧主体壳。
Two novel hexadecametal–oxygen cluster compounds, {Ni[(NH2)2(C2H4)2NH]2}3[PMoVI5MoV3VIV8O44]·[(NH2)2(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4)2NH]2}2Na[PMoVI6MoV2VIV8O44]·8H2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal–oxygen host shell is observed in 2.