Triisopropylsilanol: A new type of phase transfer catalyst for dehydrohalogenation
Triisopropylsilanol: A new type of phase transfer catalyst for dehydrohalogenation
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DOI：
10.1016/0040-4039(96)00330-9
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发表时间：
1996-04-08
影响因子：
1.8
通讯作者：
Zhang, SZ
中科院分区：
文献类型：
--
作者：
Soderquist, JA;Vaquer, J;Zhang, SZ
开发了一种新的固-液相转移催化剂三异丙基硅烷醇（TIPSOH），它通过硅烷醇/硅烷酸酯体系，使KOH能够将伯卤代烷定量转化为烯烃，避免了醚和醇的副产物。它在芥子气类似物和环境污染物的解毒中具有潜在的应用价值。版权所有（C）1996 Elsevier Science Ltd
A new solid-liquid phase transfer catalyst, trisopropylsilanol (TIPSOH), has been developed which, through the silanol/silanoate system, allows KOH to quantitatively convert even primary alkyl halides to alkenes avoiding both ether and alcohol by-products. Tts potential application in the detoxification of mustard gas analogues and environmental pollutants has been demonstrated. Copyright (C) 1996 Elsevier Science Ltd