Polymerizations with Elemental Sulfur: From Petroleum Refining to Polymeric Materials
Polymerizations with Elemental Sulfur: From Petroleum Refining to Polymeric Materials
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DOI：
10.1021/jacs.1c09329
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发表时间：
2021-12-22
影响因子：
15
通讯作者：
Pyun, Jeffrey
中科院分区：
文献类型：
--
作者：
Lee, Taeheon;Dirlam, Philip T.;Pyun, Jeffrey
从石油精炼中生产元素硫创造了一个技术机会，通过合成具有改进的光学、电化学和机械性能的高性能硫基塑料来提高元素硫的价值，目的是应用于热成像、能量储存、自修复材料和分离科学。在这个角度来看，我们讨论了在过去的十年中，已经恢复了这一领域的有机硫和聚合物化学提供了一类新的高硫含量的聚合物制备的液体硫与不饱和单体的聚合，称为反硫化的努力。
The production of elemental sulfur from petroleum refining has created a technological opportunity to increase the valorization of elemental sulfur by the synthesis of high-performance sulfur-based plastics with improved optical, electrochemical, and mechanical properties aimed at applications in thermal imaging, energy storage, self-healable materials, and separation science. In this Perspective, we discuss efforts in the past decade that have revived this area of organosulfur and polymer chemistry to afford a new class of high-sulfur-content polymers prepared from the polymerization of liquid sulfur with unsaturated monomers, termed inverse vulcanization.