THE EFFECT OF ANTISYMMETRIC EXCHANGE ON THE ELECTRON-PARAMAGNETIC-RES SPECTRA OF COUPLED PAIRS OF TRANSITION-METAL IONS
THE EFFECT OF ANTISYMMETRIC EXCHANGE ON THE ELECTRON-PARAMAGNETIC-RES SPECTRA OF COUPLED PAIRS OF TRANSITION-METAL IONS
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DOI：
10.1080/00268978200100112
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发表时间：
1982-01-01
影响因子：
1.7
通讯作者：
GATTESCHI, D
中科院分区：
文献类型：
--
作者：
BENCINI, A;GATTESCHI, D
The antisymmetric exchange term (AET) in the exchange spin hamiltonian,d. S1×S2, can have sizeable effects on the EPR spectra of hetero-dinuclear transition metal complexes. In this paper we review briefly the symmetry aspects of the AET and give a general formulation for its matrix elements for any pair ofS1,S2values. The effects of the AET on the E.P.R. spectra are discussed and one case where its presence can be recognized is shown.
