The Linear Jahn-Teller Effect for an Orbital Triplet

The Linear Jahn-Teller Effect for an Orbital Triplet
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轨道三重态的线性 Jahn-Teller 效应

DOI:
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发表时间:
1973
期刊:
November 1
影响因子:
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通讯作者:
V. Polinger
V. Polinger
中科院分区:
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文献类型:
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作者:
I. Bersuker;V. Polinger

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本文给出了一个与四角振动和三角振动都线性耦合的三重态轨道的Jahn-Teller振动问题的研究结果,其中e型振动耦合常数是任意的,而tz振动耦合常数被假定为很小.准确地总结了所有二阶微扰系列。计算了基态和几个激发态的能量和波函数以及约化因子。后者似乎是非常敏感的耦合常数的变化。 [俄语文本忽略]
The results of a Jahn-Teller vibronic problem investigation for an orbital triplet linearly coupled to both a tetragonal e- and trigonal tz-vibration are given, the e-type vibroni ccoupling constant being taken arbitrary, while the tz one is assumed to be small. All the second order perturbation seria are summarized exactly. The ground and several excited state energies and wave functions as well as the reduction factors are calculated. The latter seems to be very sensible to the variation of the coupling constants. [Russian Text Ignored]