The Linear Jahn-Teller Effect for an Orbital Triplet
The Linear Jahn-Teller Effect for an Orbital Triplet
复制标题
轨道三重态的线性 Jahn-Teller 效应
DOI:
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发表时间:
1973
期刊:
影响因子:
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通讯作者:
V. Polinger
中科院分区:
文献类型:
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作者:
I. Bersuker;V. Polinger
The results of a Jahn-Teller vibronic problem investigation for an orbital triplet linearly coupled to both a tetragonal e- and trigonal tz-vibration are given, the e-type vibroni ccoupling constant being taken arbitrary, while the tz one is assumed to be small. All the second order perturbation seria are summarized exactly. The ground and several excited state energies and wave functions as well as the reduction factors are calculated. The latter seems to be very sensible to the variation of the coupling constants.
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