Curie temperature measurements on KTiOPO4 single crystals grown by flux and hydrothermal techniques

Curie temperature measurements on KTiOPO4 single crystals grown by flux and hydrothermal techniques
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通过助熔剂和水热技术生长的 KTiOPO4 单晶的居里温度测量

DOI:
10.1080/00150199108014472
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发表时间:
1991
期刊:
影响因子:
--
通讯作者:
M. Fejer
M. Fejer
中科院分区:
--
文献类型:
--
作者:
P. Bordui;R. Norwood;M. Fejer

文献摘要

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测量了多种KTiOPO 4晶体的居里温度,其范围为947 ~ 960°C。Tc一般高于水热比助熔剂生长的晶体。随着持续的测量,Tc下降的热液样品和增加的助熔剂生长的样品。对于这两种类型的样品,在连续居里测量24小时后,在吸收光谱中在2.814 μm处出现额外的偏振敏感线。Tc在KTiOPO 4被发现是一个敏感的函数的测量参数,包括在温度下的时间,样品厚度,施加的电场,和周围的气氛。
Abstract Curie temperatures of a variety of KTiOPO4 crystals were measured to range from 947 to 960°C. Tc was generally higher for hydrothermal than for flux-grown crystals. With continued measurement, Tc decreased for hydrothermal samples and increased for flux-grown samples. For both types of samples, after 24 hours of continuous Curie measurement an additional polarization-sensitive line appeared in the absorption spectrum at 2.814 μm. Tc in KTiOPO4 was found to be a sensitive function of measurement parameters including time at temperature, sample thickness, applied electric field, and surrounding atmosphere.