New exo/endo selectivity observed in monohydrolysis of dialkyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates

New exo/endo selectivity observed in monohydrolysis of dialkyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates
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DOI:
10.1016/j.tetlet.2003.09.131
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发表时间:
2003-11-17
影响因子:
1.8
通讯作者:
Hiraga, Y
Hiraga, Y
中科院分区:
化学4区
文献类型:
--
作者:
Niwayama, S;Hiraga, Y

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几种外或内双环[2.2.1]庚-5-烯-2,3-二羧酸二甲酯或二乙酯的新单水解反应显示出对外烷氧羰基单水解的更高选择性,尽管反应中心位于远离异戊烯环的位置。(C)2003 Elsevier Ltd.保留所有权利。
New monohydrolysis reactions of several exo or endo dimethyl or diethyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylates showed higher selectivity toward monohydrolyses of exo-carboalkoxy groups, although the reaction centers are located away from the norbornene rings. (C) 2003 Elsevier Ltd. All rights reserved.