Sulfur(IV)-Mediated Transformations: From Ylide Transfer to Metal-Free Arylation of Carbonyl Compounds
Sulfur(IV)-Mediated Transformations: From Ylide Transfer to Metal-Free Arylation of Carbonyl Compounds
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DOI：
10.1021/ja4017683
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发表时间：
2013-05-15
影响因子：
15
通讯作者：
Maulide, Nuno
中科院分区：
文献类型：
--
作者：
Huang, Xueliang;Patil, Mahendra;Maulide, Nuno
从统一的角度介绍了直接酰基转移到羰基衍生物和亚砜介导的芳基化的发展。机理研究（包括密度泛函计算）支持一个共同的反应途径，并展示了反应物性质的细微变化如何导致不同的和看似不相关的反应结果。
The development of a direct ylide transfer to carbonyl derivatives and of a sulfoxide-mediated arylation is presented from a unified perspective. Mechanistic studies (including density functional calculations) support a common reaction pathway and showcase how subtle changes in reactant properties can lead to disparate and seemingly unrelated reaction outcomes.