THE SYNTHESIS OF HOMOISOTWISTANES BY THE TANDEM WESSELY OXIDATION - DIELS-ALDER REACTION SEQUENCE
THE SYNTHESIS OF HOMOISOTWISTANES BY THE TANDEM WESSELY OXIDATION - DIELS-ALDER REACTION SEQUENCE
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DOI：
10.1016/0040-4039(91)80006-r
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发表时间：
1991-08-26
影响因子：
1.8
通讯作者：
YATES, P
中科院分区：
文献类型：
--
作者：
BHAMARE, NK;GRANGER, T;YATES, P
将5-（2-羟基苯基）-1-戊烯和-1-戊烯-3-酮进行Wessely氧化，然后进行分子内Diels-Alder反应，得到高异戊烯;将5-（2-羟基苯基）-3-亚甲基-1-戊烯进行类似的处理，得到二十烯和异戊烯衍生物。
Wessely oxidation of 5-(2-hydroxyphenyl)-1-pentene and -1-penten-3-ones followed by intramolecular Diels-Alder reactions gave homoisotwistanes; similar treatment of 5-(2-hydroxyphenyl)-3-methylene-1-pentene gave twistane and isotwistane derivatives.