Study of structure and properties of modified borophosphate glasses

Study of structure and properties of modified borophosphate glasses
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DOI:
10.1088/1757-899x/2/1/012015
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发表时间:
2009-07
期刊:
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影响因子:
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通讯作者:
L. Koudelka;P. Mošner;J. Šubčík
L. Koudelka;P. Mošner;J. Šubčík
中科院分区:
其他
文献类型:
--
作者:
L. Koudelka;P. Mošner;J. Šubčík

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本文综述了锌、铅硼磷酸盐玻璃的结构和性能的研究进展。应用拉曼和红外光谱以及31 P和11 B MAS NMR光谱对几种硼磷酸盐玻璃进行了结构研究。在几个组成系列中实现了结构研究,从而建立了玻璃中基本结构单元的组成依赖性和演变。介绍了用其它氧化物如Sb_2O_3和过渡金属氧化物如TiO_2和Nb_2O_5对磷酸盐和硼磷酸盐玻璃进行改性。
A review on the investigation of the structure and properties of zinc and lead borophosphate glasses is given. Structural studies with the application of Raman and infrared spectroscopy and 31P and 11B MAS NMR spectroscopy are manifested on several borophosphate glasses. Structural studies were realized in several compositional series and thus compositional dependencies and the evolution of basic structural units in the glasses was established. The modification of phosphate and borophosphate glasses with other oxides e.g. Sb2O3 and transition metal oxides like TiO2 and Nb2O5 is presented.