Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis
Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis
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DOI：
10.1039/b923189g
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Love, Jason B.
中科院分区：
文献类型：
--
作者：
Askarizadeh, Elham;Yaghoob, Sahar Bani;Love, Jason B.
通过修饰大环二钴Pacman络合物的口，可以分离新的桥接-超氧和羟基络合物，并调节该系统对催化四电子还原双氧为水的反应性。
By modifying the mouth of a macrocyclic dicobalt Pacman complex, it is possible to both isolate new bridging-superoxo and hydroxyl complexes and to tune the reactivity of this system towards catalytic four-electron reduction of dioxygen to water.