Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide
Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide
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DOI：
10.1039/d0cc01753a
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发表时间：
2020-05-11
影响因子：
4.9
通讯作者：
Horike, Satoshi
中科院分区：
文献类型：
--
作者：
Kadota, Kentaro;Sivaniah, Easan;Horike, Satoshi
含硼氢化物（BH 4-）的配位聚合物将CO2转化为HCO 2-或[BH 3（OCHO）]（-），其反应路线受金属离子电负性和BH 4-配位方式的影响。反应进行了研究，使用热重分析下的CO2气流，红外光谱，和NMR实验。
Borohydride (BH4-)-containing coordination polymers converted CO2 into HCO2- or [BH3(OCHO)](-), whose reaction routes were affected by the electronegativity of metal ions and the coordination mode of BH4-. The reactions were investigated using thermal gravimetric analysis under CO2 gas flow, infrared spectroscopy, and NMR experiments.