Ferro- and ferri-magnetism in oximato-bridged MIIICuII chains (M = Mn and Fe). A molecular based ferromagnet with Tc= 9 K: [MnIIICuII-bis(1,2-cyclohexanedioneoximato)(acetato)(H2O)2]

Ferro- and ferri-magnetism in oximato-bridged MIIICuII chains (M = Mn and Fe). A molecular based ferromagnet with Tc= 9 K: [MnIIICuII-bis(1,2-cyclohexanedioneoximato)(acetato)(H2O)2]
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肟桥 MIIICuII 链中的铁磁性和亚铁磁性(M = Mn 和 Fe)。

DOI:
10.1039/c39940002615
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发表时间:
1994
期刊:
Journal of The Chemical Society, Chemical Communications
影响因子:
--
通讯作者:
M. Verdaguer
M. Verdaguer
中科院分区:
--
文献类型:
--
作者:
F. Lloret;R. Ruiz;B. Cervera;I. Castro;M. Julve;J. Faus;J. Real;F. Sapiña;Y. Journaux;J. Colin;M. Verdaguer

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对化合物[MⅢCuII(L)2(MeCO_2)(H_2O)_2],M=Mn和L=二甲基乙二酮肟(Dmg)_1或1,2-环己二酮肟(CHD)_2和M=Fe和L=dMg_3的磁性研究表明,1为亚磁性化合物,2为体铁磁体,T_c=9K,7.5K时为三级反铁磁。
The study of the magnetic properties of the compounds [MIIICuII(L)2(MeCO2)(H2O)2], M = Mn and L = dimethylglyoximato (dmg)1 or 1,2-cyclohexanedioneoximato (chd)2 and M = Fe and L = dmg 3, shows that 1 is a metamagnetic compound, 2 is a bulk ferromagnet with Tc= 9 K and 3 orders antiferromagnetically at 7.5 K.