碳龙配合物的烯基化研究
碳龙配合物的烯基化研究
复制标题
烯属碳龙配合物的合成
DOI：
10.6023/cjoc201703003
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
夏海平
中科院分区：
文献类型：
--
作者：
路正宇;陈江溪;夏海平
碳龙配合物是一种新型的金属芳香族化合物，具有新颖的骨架和有趣的性质，可以作为潜在的有趣材料。然而，它们大多不具有活性有机官能团，这阻碍了它们通过化学修饰作为功能材料的应用。烯烃基团是一种反应性官能团，可用于聚合反应或咔嗒反应等。本文报道了基于反应性的碳龙配合物的合成，该配合物可用于制备含碳龙材料。
Carbolong complexes are a new type of metalla-aromatic compounds with novel skeleton and interesting properties, which could be used as potential interesting materials. However, most of them do not have reactive organic functional groups, which hinder their applications as functional materials via chemical modifications. Olefinic group is a reactive functional group that can be used for polymerization or click reaction and so on. In this work, the synthesis of carbolong complexes attached an olefinic group, which could be used to prepare carbolong-containing materials, is reported based on their reactivity.