Synthesis of ordered ultrathin ZnO nanowire bundles on an indium-tin oxide substrate

Synthesis of ordered ultrathin ZnO nanowire bundles on an indium-tin oxide substrate
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DOI:
10.1021/ic7019236
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发表时间:
2008-01-21
影响因子:
4.6
通讯作者:
Li, Binghui
Li, Binghui
中科院分区:
化学2区
文献类型:
--
作者:
Fang, Fang;Zhao, Dongxu;Li, Binghui

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在没有任何催化剂的情况下,采用简单的热蒸发方法在铟锡氧化物衬底上制备了超细ZnO纳米线束,在ZnO纳米柱的六角头部生长了自组织的ZnO纳米线束。所获得的纳米线通常具有8nm的直径,长度延伸至0.25 μ m。该尺寸与ZnO激子玻尔半径(a(B))的数量级相同。室温光致发光测量显示在374 nm(3.32 eV),这是约100 meV的蓝移从体ZnO发射的一个突出的峰。
Ultrathin ZnO nanowire bundles have been synthesized on an indium-tin oxide substrate without any catalyst by using a simple thermal evaporation method, where self-organized ZnO nanowire bundles were grown on the hexagonal heads of ZnO nanocolumns. The nanowires obtained typically have diameters of 8 nm, with lengths extending to 0.25 mu m. The size is the same order of magnitude as the ZnO exciton Bohr radius (a(B)). Room-temperature photoluminescence measurement shows a prominent peak at 374 nm (3.32 eV), which is about 100 meV blue-shifted from the bulk ZnO emission.