Stereospecificity and mechanism in cation radical Diels-Alder and cyclobutanation reactions
Stereospecificity and mechanism in cation radical Diels-Alder and cyclobutanation reactions
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DOI：
10.1021/ol9907567
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发表时间：
1999-09-09
期刊：
影响因子：
5.2
通讯作者：
Yang, JK
中科院分区：
文献类型：
--
作者：
Bauld, NL;Yang, JK
[图]阳离子自由基diols - alder和环丁化反应的顺式和反式-1,2-（二氧基）乙烯与一个环和一个非环二烯已被发现是立体特异性的，符合一致的环加成机制。
[GRAPHICS]The cation radical Diels-Alder and cyclobutanation reactions of cis- and trans-1,2-(diaryloxy)ethenes with a cyclic and an acyclic diene have been found to be stereospecific, in accord with a concerted cycloaddition mechanism.