Solid State Electrochemistry I: Thermodynamics and Kinetics of Charge Carriers in Solids
Solid State Electrochemistry I: Thermodynamics and Kinetics of Charge Carriers in Solids
复制标题
固态电化学 I：固体中载流子的热力学和动力学
DOI：
10.1007/0-387-25838-8_1
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发表时间：
2005
期刊：
影响因子：
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通讯作者：
J. Maier
中科院分区：
文献类型：
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作者：
J. Maier
这一贡献涉及热力学和动力学的电荷载体在固体的情况下，零或非零的电力或化学驱动力。它不打算重复众所周知的电化学原理，然而，它打算强调固体中的特殊情况，一方面强调由于固体性质而产生的特征方面，另一方面，在必要时强调图像的共同和概括方面。这也意味着，具体的固态方面（如结构细节，各向异性或应变效应）被忽略时，他们的影响是不是必不可少的理解。目前的贡献不包括固态技术来测量电化学参数，也不考虑固态电化学的应用。这些专题将在第二部分中讨论，该部分将单独发表。1
This contribution deals with thermodynamics and kinetics of charge carriers in solids in the case of zero or non-zero electrical or chemical driving forces. It does not intend to repeat well-known electrochemical principles, however, it intends to underline the special situation in solids by, on one hand, emphasizing characteristic aspects due to the solid nature, but on the other hand, stressing the common and generalizing aspects of the picture whenever it appears necessary. This also implies that specific solid state aspects (such as structural details, anisotropies or strain effects) are neglected whenever their influence is not indispensable for the understanding. The present contribution does not include solid state techniques to measure electrochemical parameters, nor does it consider applications of solid state electrochemistry. Such topics will be dealt with in a second part which will appear separately. 1