Preparation of 2-Substituted 3-Methoxycarbonyl-4-methoxyfurans that Allow Access to Highly Functionalized Naphthalenes via Regioselective Cycloaddition with Alkoxybenzyne
Preparation of 2-Substituted 3-Methoxycarbonyl-4-methoxyfurans that Allow Access to Highly Functionalized Naphthalenes via Regioselective Cycloaddition with Alkoxybenzyne
复制标题
制备 2-取代 3-甲氧基羰基-4-甲氧基呋喃,通过与烷氧基苯炔的区域选择性环加成反应获得高度官能化的萘
DOI:
10.1055/s-0036-1590825
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发表时间:
2017
期刊:
影响因子:
2
通讯作者:
Keisuke Suzuki
中科院分区:
文献类型:
--
作者:
Shogo Sato;Takuma Kawada;Hiroshi Takikawa;Keisuke Suzuki
A facile synthetic method of 2-substituted 3-methoxycarbonyl-4-methoxyfurans has been developed, allowing construction of highly functionalized naphthalene derivatives via (1) regioselective benzyne [4+2] cycloaddition with α-alkoxybenzyne and (2) reductive aromatization.