Synthesis of isoflavonoids.: Enantiopure cis- and trans-6a-hydroxypterocarpans and a racemic trans-pterocarpan

Synthesis of isoflavonoids.: Enantiopure cis- and trans-6a-hydroxypterocarpans and a racemic trans-pterocarpan
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DOI:
10.1016/s0040-4020(01)00679-2
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发表时间:
2001-08-13
期刊:
影响因子:
2.1
通讯作者:
Ferreira, D
Ferreira, D
中科院分区:
化学3区
文献类型:
--
作者:
van Aardt, TG;van Rensburg, H;Ferreira, D

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苯乙酸酯和苯甲醛之间的羟醛缩合得到2,3-二芳基-3-羟基丙酸酯,其用作第一外消旋反式紫檀烷和对映纯顺式和反式-6 α-羟基紫檀烷的共同前体。(C)2001爱思唯尔科技有限公司版权所有。
Aldol condensation between phenylacetates and benzaldehydes affords 2,3-diaryl-3-hydroxypropanoates which serve as common precursors to both the first racemic trans-pterocarpan and enantiopure cis- and trans-6a-hydroxypterocarpans. (C) 2001 Elsevier Science Ltd. All rights reserved.