AROMATIC MOLECULES BEARING SUBSTITUENTS WITHIN CAVITY OF PI-ELECTRON CLOUD . SYNTHESIS OF TRANS-15,16-DIMETHYLDIHYDROPYRENE
AROMATIC MOLECULES BEARING SUBSTITUENTS WITHIN CAVITY OF PI-ELECTRON CLOUD . SYNTHESIS OF TRANS-15,16-DIMETHYLDIHYDROPYRENE
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DOI：
10.1021/ja00983a028
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发表时间：
1967-01-01
影响因子：
15
通讯作者：
PHILLIPS, JB
中科院分区：
文献类型：
--
作者：
BOEKELHE.V;PHILLIPS, JB
报道了反式-5，16-二甲基二氢芘(1)的合成方法。根据包括光谱性质和化学反应活性在内的所有常见标准，反式-L 5，16-二甲基二氢芘是一种芳香族分子。这是芳香族分子在7R电子云腔内具有取代基的第一个例子。
A synthesis of trans-\5, l6-dimethyldihydropyrene (1) is described. By all of the common criteria, including both spectral properties and chemical reactivity, trans-l 5, 16-dimethyldihydropyrene is an aromatic molecule. This is the first example of an aromatic molecule having substituents within the cavity of the 7r-electron cloud.