Lamellar-in-lamellar self-assembled C–b–(B–b–A)m–b–B–b–C multiblock copolymers: Alexander–de Gennes approach and dissipative particle dynamics simulations

Lamellar-in-lamellar self-assembled C–b–(B–b–A)m–b–B–b–C multiblock copolymers: Alexander–de Gennes approach and dissipative particle dynamics simulations
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DOI:
10.1039/b809751h
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发表时间:
2009
期刊:
影响因子:
3.4
通讯作者:
T. Klymko;V. Markov;A. Subbotin;G. Brinke
T. Klymko;V. Markov;A. Subbotin;G. Brinke
中科院分区:
化学2区
文献类型:
--
作者:
T. Klymko;V. Markov;A. Subbotin;G. Brinke

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A simple theoretical analysis of the lamellar-in-lamellar self-assembled state of ternary C–b–(B–b–A)m–b–B–b–C multiblock copolymer melts in the strong segregation limit is presented using the Alexander–de Gennes approximation. For a given value of m, the influence of the chain length of the various blocks and the value of the Flory–Huggins χAB and χBC interaction parameters on the number k of internal domains is discussed in detail. The theoretically predicted tendencies are corroborated by computer simulations using the dissipative particle dynamics technique.