Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
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DOI：
10.1039/c0ob00176g
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发表时间：
2010-09
影响因子：
3.2
通讯作者：
中科院分区：
文献类型：
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作者：
采用Pd（OAc）2/HPMoV/O 2催化体系，以分子氧为末端氧化剂，通过直接活化苯的C-H键，成功地实现了由丙烯腈和苯直接合成肉桂腈。
A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant.