Highly efficient synthesis of medium-sized lactones via oxidative lactonization: concise total synthesis of isolaurepan
Highly efficient synthesis of medium-sized lactones via oxidative lactonization: concise total synthesis of isolaurepan
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DOI：
10.1039/b919673k
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发表时间：
2010-01-01
影响因子：
3.2
通讯作者：
Sasaki, Makoto
中科院分区：
文献类型：
--
作者：
Ebine, Makoto;Suga, Yuto;Sasaki, Makoto
在Phi(OAc)(2)催化下，TEMPO催化1，6-和1，7-二醇的氧化内酯反应，分别以较高的产率分别得到七元和八元内酯。
A catalytic amount of TEMPO in the presence of PhI(OAc)(2) effected oxidative lactonization of 1,6- and 1,7-diols, directly affording seven- and eight-membered lactones, respectively, in good yields.