Comparison of the Catalytic Behaviors of Single Cubane MoFe3S4 and Fe4S4 Clusters toward the Multi-electron Reduction of n-C5H11N3
Comparison of the Catalytic Behaviors of Single Cubane MoFe3S4 and Fe4S4 Clusters toward the Multi-electron Reduction of n-C5H11N3
复制标题
单古巴烷MoFe3S4和Fe4S4团簇对n-C5H11N3多电子还原的催化行为比较
DOI：
10.1246/cl.1987.373
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发表时间：
1987
影响因子：
1.6
通讯作者：
Toshio Tanaka
中科院分区：
文献类型：
--
作者：
Koji Tanaka;M. Moriya;Toshio Tanaka
在含有甲基紫精和[MoFe 3S 4（S-p-n-C6 H4 C8 H17）3（O2 C6 Cl 4）（Me 2CO）]2-（1）或[Fe 4S 4（S-p-n-C6 H4 C8 H17）4]2-（2）的Triton X-100胶束水溶液中研究了Na 2S 2 O 4还原n-C5 H11 N3的反应。1催化n-C_5 H_（11）N_3的两电子还原，也催化6电子和8电子还原，生成n-C_5 H_（11）NH_2、N_2、N_2 H_4和NH_3，而2催化n-C_5 H_（11）N_3的两电子还原。
The reduction of n-C5H11N3 by Na2S2O4 was investigated in an aqueous Triton X-100 micellar solution containing methylviologen and [MoFe3S4(S-p-n-C6H4C8H17)3(O2C6Cl4)(Me2CO)]2− (1) or [Fe4S4(S-p-n-C6H4C8H17)4]2− (2). 1 catalyzes the reduction of n-C5H11N3 not only with two electrons but also with six and eight electrons to afford n-C5H11NH2, N2, N2H4, and NH3, while 2 catalyzes only two electron reduction of n-C5H11N3.